Tsb

2CaCO3

Calcium hydroxide

Calcium carbonate

Water

Calcium carbonate formed by this reaction is insoluble and can be removed by gravity separation (settling). The typical settling time is 30 min or less, but most systems are designed for continuous operation with typical detention times of 1 hr.

Water treatment with this process is called excess-lime softening because the application of lime is in excess of that required for the reaction described in Equation 7.42(11). Control consists of adding sufficient calcium hydroxide to maintain an excess hydroxide alkalinity of 10 to 50 mg/l, as shown in the following equation:

where P is the phenolphthalein alkalinity and MO is the methyl orange alkalinity. This addition results in a pH value of 10 to 11, but pH control is not satisfactory for economical operations. In this example, suitable analyti-

FIG. 7.42.11 Calcium carbonate precipitation control system. Details of the carbon dioxide feeder are shown in Figure 7.42.3.

cal instrumentation is not available for continuous system control. If the quality of the untreated water varies, operator control of the lime dosage is essential. Wastewater treatment facilities usually pace the manual dosage by feedforward control from the flow rate.

A factor in calcium carbonate precipitation is a chemical phenomenon known as crystal seeding. This factor involves the acceleration of carbonate crystal formation by the presence of previously precipitated crystals. Wastewater treatment facilities accomplish crystal seeding in practice by passing the water being treated through a sludge blanket in an upflow treatment unit, shown schematically in Figure 7.42.11. The resulting crystals of calcium carbonate are hard, dense, and discrete, and they separate readily.

When colloidal suspended material is also to be removed, which occurs when surface waters are softened, water treatment facilities also add a coagulant of aluminum, iron salts, or polymers to precipitate the colloids.

The dosage varies depending on the quantity of suspended material. The application of both coagulant and calcium hydroxide is controlled by flow-ratio modulation.

The resulting sludge, consisting of calcium carbonate, aluminum, or iron hydroxides, and the precipitated colloidal material are discharged to waste continuously. As previously noted, the presence of some precipitated carbonate is beneficial to remove all sludge. The use of an automatic level control system (see Figure 7.42.11) controls the sludge level at an optimum.

Water softened by excess-lime treatment is saturated with calcium carbonate and is therefore unstable. Water treatment facilities can achieve stability by adding carbon dioxide to convert a portion of the carbonates into bicarbonate, according to the following equation:

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